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Position: Home > issue > May 10, 2022 Volume 3, Issue 3
Azetidine synthesis enabled by photo-induced copper catalysis via [3+1] radical cascade cyclization
Category:   Report   Download:  PDF  Figure  Endnote
Author: Jianye Li, Lu Yu, Yun Peng, Bin Chen, Rui Guo, Xiaodong Ma, Xiao-Song Xue, Yunkui Liu, Guozhu Zhang

101.jpg

Graphical abstract


Azetidines are an important type of saturated, highly strained, four-membered, nitrogen-containing heterocyclic compound. These compounds serve as important raw materials, intermediates, and catalysts in organic synthesis, as well as important active units in amino acids, alkaloids, and pharmaceutically active compounds. Thus, the development of an efficient and concise method to construct azetidines is of great significance in multiple disciplines. In this work, we reported on the photo-induced copper-catalyzed radical annulation of aliphatic amines with alkynes to produce azetidines.





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