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Position: Home > issue > May 10, 2022 Volume 3, Issue 4
Demetallation of organometallic and metal-mediated reactions
Category:   Perspective   Download:  PDF  Figure  Endnote
Author: Chao-Jun Li

52.jpg

Classical organometallic reactions and organometallic-type reactions without using stoichiometric metals


The use of stoichiometric organometallic reagents and stoichiometric metals formed the basis of vast majority of classical reactions for constructing carbon¨Ccarbon bonds. The indispensable requirement of stoichiometric metals for such reactions constitutes significant challenges in terms of resource sustainability, operational safety, and chemical-waste management. The recent developments in C¨CH functionalizations, hydrogenative alkene/alkyne addition to electrophiles, the hydrazone umpolung chemistry, and other emerging fields such as the electrosynthesis and photoredox chemistry provide potential solutions to overcome these inherent challenges.





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