Strategies for enhancing electrochemical CO2 reduction to multi-carbon fuels on copper

Xin Li; Yuxin Chen; Xinyu Zhan; Yiwen Xu; Leiduan Hao; Liang Xu; Xueying Li; Muhammad Umer; Xinyi Tan; Buxing Han; Alex W. Robertson; Zhenyu Sun

doi:10.59717/j.xinn-mater.2023.100014

The Innovation Materials > 2023 Vol. 1 > No. 1 > 100014

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Strategies for enhancing electrochemical CO₂ reduction to multi-carbon fuels on copper

1.
State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2.
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing Key Laboratory of Environmental Science and Engineering, Beijing 100081, China
3.
Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
4.
Department of Physics, University of Warwick, Coventry CV 47AL, UK
5.
These authors contribute equally

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Corresponding authors: xinyitan@bit.edu.cn (X.T.); hanbx@iccas.ac.cn (B.H.); sunzy@mail.buct.edu.cn (Z.S.)
Received Date: April 04, 2023

Accepted Date: May 15, 2023

Published Online: June 05, 2023

The Innovation Materials 1(1), https://doi.org/10.59717/j.xinn-mater.2023.100014 | Cite this article

GRAPHICAL ABSTRACT

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PUBLIC SUMMARY

PUBLIC SUMMARY
1. Avenues to boost CO₂ electroreduction to C₂₊ products are summarized.
  
  How the catalyst structure can be designed to enhance performance is discussed.
  
  Opportunities in the electroreduction of CO₂ into multi-carbon fuels are presented.

ABSTRACT

ABSTRACT

Productively harnessing CO₂ as a reactant is of practical interest due to addressing the dual pressures of resource sustainability and environmental sustainability. Electrochemical CO₂ reduction (ECR) offers a promising approach for driving the chemical transformation of CO₂ by exploiting green renewably generated electricity at (near) room temperature and ambient pressure, facilitating a sustainable, low-carbon footprint future. In this work, we provide a comprehensive and timely review of the various avenues that have been developed to date to modulate product selectivity, stability, and efficiency toward C₂₊ using Cu-based electrocatalysts. We discuss how the electrocatalyst structure can be effectively designed in order to boost performance. Special attention is paid to some of the critical intermediate species that shed light on CO₂ reduction paths. We will also discuss the application of in situ and operando spectroscopy, along with computational techniques, that help to improve our fundamental understanding of ECR. Finally, development opportunities and challenge in the conversion of CO₂ into multi-carbon fuels by Cu-based electrocatalysts are presented.

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Li X., Chen Y., Zhan X., et al., (2023). Strategies for enhancing electrochemical CO2 reduction to multi-carbon fuels on copper. The Innovation Materials 1(1), 100014. https://doi.org/10.59717/j.xinn-mater.2023.100014

Li X., Chen Y., Zhan X., et al., (2023). Strategies for enhancing electrochemical CO₂ reduction to multi-carbon fuels on copper. The Innovation Materials 1(1), 100014. https://doi.org/10.59717/j.xinn-mater.2023.100014

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