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Effect of symmetry breaking on Dirac points in topological semimetal EuAgBi

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    1. Symmetry-breaking-driven topological phase transitions were observed in EuAgBi and BaAgBi.

      Transformations among centrosymmetric and noncentrosymmetric Dirac points and Weyl points were observed.

      Noncentrosymmetric Dirac points were confirmed by angle-resolved photoemission spectroscopy.

  • Combining symmetry breaking with topological theory constitutes a promising approach for advancing the understanding and control of topological phase transitions, which calls for experimental evidence from suitable material systems. We investigated Dirac points (DP) in noncentrosymmetric EuAgBi through the breaking of inversion symmetry (P), time-reversal symmetry (T), and sixfold rotational symmetry (C6), using centrosymmetric BaAgBi as the reference. The analysis of various magnetic structures in EuAgBi achieved by controlling temperature and magnetic field shows that breaking P does not affect the existence of DP; breaking both P and T transforms DP into Weyl points (WP); and despite the reduced symmetry when P, T, and C6 are all broken, WP remains formally unaffected in the field-induced ferromagnetic phase. Additionally, we have realized the possible coexistence of WP and DP along distinct directions. Furthermore, the noncentrosymmetric (P-broken) DP, previously predicted theoretically but lacking experimental evidence, were observed in paramagnetic EuAgBi using angle-resolved photoemission spectroscopy. Our results provide realistic examples of how distinct topological states can emerge under different symmetry-breaking scenarios.
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  • [1] Wen X.-G. (2007). Quantum field theory of many-body systems: From the origin of sound to an origin of light and electrons (Oxford University Press). DOI: 10.1093/acprof:oso/9780199227259.001.0001

    View in Article Google Scholar

    [2] Hasan M. Z. and Kane C. L. (2010). Colloquium: Topological insulators. Rev. Modern Phys. 82:3045−3067. DOI:10.1103/RevModPhys.82.3045

    View in Article CrossRef Google Scholar

    [3] Wang X., Li B., Zhou L., et al. (2023). Structure, physical properties, and magnetically tunable topological phases in the topological semimetal EuCuBi. Phys. Rev. B 108:115126. DOI:10.1103/PhysRevB.108.115126

    View in Article CrossRef Google Scholar

    [4] Chen H., Gao J., Chen L., et al. (2022). Topological crystalline insulator candidate ErAsS with hourglass fermion and magnetic-tuned topological phase transition. Adv. Mater. 34:2110664. DOI:10.1002/adma.202110664

    View in Article CrossRef Google Scholar

    [5] Yang B.-J. and Nagaosa N. (2014). Classification of stable three-dimensional Dirac semimetals with nontrivial topology. Nat. Commun. 5:4898. DOI:10.1038/ncomms5898

    View in Article CrossRef Google Scholar

    [6] Qi X.-L. and Zhang S.-C. (2011). Topological insulators and superconductors. Rev. Mod. Phys. 83:1057−1110. DOI:10.1103/RevModPhys.83.1057

    View in Article CrossRef Google Scholar

    [7] Schnyder A. P., Ryu S., Furusaki A., et al. (2008). Classification of topological insulators and superconductors in three spatial dimensions. Phys. Rev. B 78:195125. DOI:10.1103/PhysRevB.78.195125

    View in Article CrossRef Google Scholar

    [8] Shen J., Gao J., Yi C., et al. (2023). Magnetic-field modulation of topological electronic state and emergent magneto-transport in a magnetic Weyl semimetal. The Innovation 4:100399. DOI:10.1016/j.xinn.2023.100399

    View in Article CrossRef Google Scholar

    [9] Jin Y. J., Zheng B. B., Xiao X. L., et al. (2020). Two-dimensional Dirac semimetals without inversion symmetry. Phys. Rev. Lett. 125:116402. DOI:10.1103/PhysRevLett.125.116402

    View in Article CrossRef Google Scholar

    [10] Borisenko S., Gibson Q., Evtushinsky D., et al. (2014). Experimental realization of a three-dimensional Dirac semimetal. Phys. Rev. Lett. 113:027603. DOI:10.1103/PhysRevLett.113.027603

    View in Article CrossRef Google Scholar

    [11] Jeon S., Zhou B. B., Gyenis A., et al. (2014). Landau quantization and quasiparticle interference in the three-dimensional Dirac semimetal Cd3As2. Nat. Mater. 13:851−856. DOI:10.1038/nmat4023

    View in Article CrossRef Google Scholar

    [12] Liu Z. K., Jiang J., Zhou B., et al. (2014). A stable three-dimensional topological Dirac semimetal Cd3As2. Nat. Mater. 13:677−681. DOI:10.1038/nmat3990

    View in Article CrossRef Google Scholar

    [13] Liu Z. K., Zhou B., Zhang Y., et al. (2014). Discovery of a three-dimensional topological Dirac semimetal, Na3Bi. Science 343:864−867. DOI:10.1126/science.1245085

    View in Article CrossRef Google Scholar

    [14] Neupane M., Xu S.-Y., Sankar R., et al. (2014). Observation of a three-dimensional topological Dirac semimetal phase in high-mobility Cd3As2. Nat. Commun. 5:3786. DOI:10.1038/ncomms4786

    View in Article CrossRef Google Scholar

    [15] Roychowdhury S., Samanta K., Yanda P., et al. (2023). Interplay between magnetism and topology: large topological Hall effect in an antiferromagnetic topological insulator, EuCuAs. J. Am. Chem. Soc. 145:12920−12927. DOI:10.1021/jacs.3c04249

    View in Article CrossRef Google Scholar

    [16] Mañes J. L. (2012). Existence of bulk chiral fermions and crystal symmetry. Phys. Rev. B 85:155118. DOI:10.1103/PhysRevB.85.155118

    View in Article CrossRef Google Scholar

    [17] Morimoto T. and Furusaki A. (2014). Weyl and Dirac semimetals with topological charge. Phys. Rev. B 89:235127. DOI:10.1103/PhysRevB.89.235127

    View in Article CrossRef Google Scholar

    [18] Steinberg J. A., Young S. M., Zaheer S., et al. (2014). Bulk Dirac points in distorted spinels. Phys. Rev. Lett. 112:036403. DOI:10.1103/PhysRevLett.112.036403

    View in Article CrossRef Google Scholar

    [19] Wang Z., Weng H., Wu Q., et al. (2013). Three-dimensional Dirac semimetal and quantum transport in Cd3As2. Phys. Rev. B 88:125427. DOI:10.1103/PhysRevB.88.125427

    View in Article CrossRef Google Scholar

    [20] Young S. M., Zaheer S., Teo J. C. Y., et al. (2012). Dirac semimetal in three dimensions. Phys. Rev. Lett. 108:140405. DOI:10.1103/PhysRevLett.108.140405

    View in Article CrossRef Google Scholar

    [21] Wang Z., Sun Y., Chen X.-Q., et al. (2012). Dirac semimetal and topological phase transitions in A3Bi (A=Na, K, Rb). Phys. Rev. B 85:195320. DOI:10.1103/PhysRevB.85.195320

    View in Article CrossRef Google Scholar

    [22] Cao W., Tang P., Xu Y., et al. (2017). Dirac semimetal phase in hexagonal LiZnBi. Phys. Rev. B 96:115203. DOI:10.1103/PhysRevB.96.115203

    View in Article CrossRef Google Scholar

    [23] Gao H., Kim Y., Venderbos J. W. F., et al. (2018). Dirac-Weyl semimetal: Coexistence of Dirac and Weyl fermions in polar hexagonal ABC crystals. Phys. Rev. Lett. 121:106404. DOI:10.1103/PhysRevLett.121.106404

    View in Article CrossRef Google Scholar

    [24] Gao H., Strockoz J., Frakulla M., et al. (2021). Noncentrosymmetric topological Dirac semimetals in three dimensions. Phys. Rev. B 103:205151. DOI:10.1103/PhysRevB.103.205151

    View in Article CrossRef Google Scholar

    [25] Xia Y., Cai X. and Li G. (2020). Multitype Dirac fermions protected by orthogonal glide symmetries in a noncentrosymmetric system. Phys. Rev. B 102:041201. DOI:10.1103/PhysRevB.102.041201

    View in Article CrossRef Google Scholar

    [26] Meng L., Wu J., Li Y., et al. (2019). Dirac–Weyl semimetal phase in noncentrosymmetric transition metal monochalcogenides MoTe and WTe. J. Mater. Chem. C 7:12151−12159. DOI:10.1039/C9TC03339D

    View in Article CrossRef Google Scholar

    [27] Mondal C., Barman C. K., Alam A., et al. (2019). Broken symmetry driven phase transitions from a topological semimetal to a gapped topological phase in SrAgAs. Phys. Rev. B 99:205112. DOI:10.1103/PhysRevB.99.205112

    View in Article CrossRef Google Scholar

    [28] Barman C. K., Mondal C., Pathak B., et al. (2020). Symmetry-driven topological phases in XAgBi (X = Ba,Sr): an ab initio hybrid functional calculation. Phys. Rev. Mater. 4:084201. DOI:10.1103/PhysRevMaterials.4.084201

    View in Article CrossRef Google Scholar

    [29] Canfield P. C., Tai K., S. K. U., et al. (2016). Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples. Philos. Mag. 96:84−92. DOI:10.1080/14786435.2015.1122248

    View in Article CrossRef Google Scholar

    [30] Tomuschat C. and Schuster H.-U. (1981). ABX-verbindungen mit modifizierter Ni2In-struktur / ABX-compounds with a modified Ni2In structure. Z. Naturforschung. B. 36:1193−1194. DOI:10.1515/znb-1981-0929

    View in Article CrossRef Google Scholar

    [31] Tomuschat C. and Schuster H.-U. (1984). Magnetische eigenschaften der verbindungsreihe EuBX mit B = element der ersten neben- und X = element der fünften hauptgruppe. Z. Anorg. Allg. Chem. 518:161−167. DOI:10.1002/zaac.19845181116

    View in Article CrossRef Google Scholar

    [32] Laha A. and Hossain Z. (2018). Effect of chemical pressure on physical properties of antiferromagnetic Kondo lattice Ce2Ni3Ge5. J. Magn. Magn. Mater. 465:654−660. DOI:10.1016/j.jmmm.2018.06.054

    View in Article CrossRef Google Scholar

    [33] Tong J., Parry J., Tao Q., et al. (2014). Magnetic properties of EuCuAs single crystal. J. Alloys Compd. 602:26−31. DOI:10.1016/j.jallcom.2014.02.157

    View in Article CrossRef Google Scholar

    [34] Laha A., Singha R., Mardanya S., et al. (2021). Topological Hall effect in the antiferromagnetic Dirac semimetal EuAgAs. Physical Review B 103:L241112. DOI:10.1103/PhysRevB.103.L241112

    View in Article CrossRef Google Scholar

    [35] Malick S., Singh J., Laha A., et al. (2022). Electronic structure and physical properties of EuAuAs single crystal. Phys. Rev. B 105:045103. DOI:10.1103/PhysRevB.105.045103

    View in Article CrossRef Google Scholar

    [36] Schoop L. M., Topp A., Lippmann J., et al. Tunable Weyl and Dirac states in the nonsymmorphic compound CeSbTe. Sci. Adv. 4:eaar2317. DOI:10.1126/sciadv.aar2317

    View in Article Google Scholar

    [37] Zheng Z., Chen L., Ji X., et al. (2024). Anisotropic magnetism and band evolution induced by ferromagnetic phase transition in titanium-based kagome ferromagnet SmTi3Bi4. Sci. China Phys. , Mech. Astron. 67:267411. DOI:10.1007/s11433-023-2344-6

    View in Article CrossRef Google Scholar

    [38] Chen L., Zhou Y., Zhang H., et al. (2024). Tunable magnetism in titanium-based kagome metals by rare-earth engineering and high pressure. Commun. Mater. 5:73. DOI:10.1038/s43246-024-00513-4

    View in Article CrossRef Google Scholar

    [39] Ge Y., Jin Y. and Zhu Z. (2022). Ferromagnetic Weyl metal in EuAgP. Mater. Today Phys. 22:100570. DOI:10.1016/j.mtphys.2021.100570

    View in Article CrossRef Google Scholar

    [40] Kim J., Kim H.-S. and Vanderbilt D. (2018). Nearly triple nodal point topological phase in half-metallic GdN. Phys. Rev. B 98:155122. DOI:10.1103/PhysRevB.98.155122

    View in Article CrossRef Google Scholar

    [41] Armitage N. P., Mele E. J. and Vishwanath A. (2018). Weyl and Dirac semimetals in three-dimensional solids. Reviews of Modern Physics 90:015001. DOI:10.1103/RevModPhys.90.015001

    View in Article CrossRef Google Scholar

    [42] Dzyaloshinsky I. (1958). A thermodynamic theory of “weak” ferromagnetism of antiferromagnetics. J. Phys. Chem. Solids 4:241−255. DOI:10.1016/0022-3697(58)90076-3

    View in Article CrossRef Google Scholar

    [43] Moriya T. (1960). Anisotropic superexchange interaction and weak Ferromagnetism. Phys. Rev. 120:91−98. DOI:10.1103/PhysRev.120.91

    View in Article CrossRef Google Scholar

    [44] Liang X., Zhao L., Qiu L., et al. (2018). Skyrmions-based magnetic racetrack memory. Acta Phys. Sin-Ch. Ed. 67:137510−137510. DOI:10.7498/aps.67.20180764

    View in Article CrossRef Google Scholar

    [45] Fert A., Cros V. and Sampaio J. (2013). Skyrmions on the track. Nat. Nanotechnol. 8:152−156. DOI:10.1038/nnano.2013.29

    View in Article CrossRef Google Scholar

    [46] Lv B. Q., Qian T. and Ding H. (2021). Experimental perspective on three-dimensional topological semimetals. Rev. Mod. Phys. 93:025002. DOI:10.1103/RevModPhys.93.025002

    View in Article CrossRef Google Scholar

    [47] Song J., Park B. C., Sim K. I., et al. (2021). Tunable Berry curvature and transport crossover in topological Dirac semimetal KZnBi. npj Quantum Mater. 6:77. DOI:10.1038/s41535-021-00378-7

    View in Article CrossRef Google Scholar

    [48] Song J., Kim S., Kim Y., et al. (2021). Coexistence of Surface Superconducting and Three-Dimensional Topological Dirac States in Semimetal KZnBi. Phys. Rev. X 11:021065. DOI:10.1103/PhysRevX.11.021065

    View in Article CrossRef Google Scholar

  • Cite this article:

    Wang X., Song Z., Li W., et al. (2025). Effect of symmetry breaking on Dirac points in topological semimetal EuAgBi. The Innovation Materials 3:100171. https://doi.org/10.59717/j.xinn-mater.2025.100171
    Wang X., Song Z., Li W., et al. (2025). Effect of symmetry breaking on Dirac points in topological semimetal EuAgBi. The Innovation Materials 3:100171. https://doi.org/10.59717/j.xinn-mater.2025.100171

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