Self-assembly and tip manipulation are combined to construct atomically precise tellurium (Te) clusters.
Ring-like Te clusters on 1T’-WTe2 can be created, manipulated, and reshaped with atomic precision.
This work opens new avenues for tailoring atomic-scale assemblies and exploring emergent quantum phenomena.
| [1] | Barth J. V., Costantini G. and Kern K. (2005). Engineering atomic and molecular nanostructures at surfaces. Nature 437:671−679. DOI:10.1038/nature04166 |
| [2] | He Y., Gorman S. K., Keith D. et al. (2019). A two-qubit gate between phosphorus donor electrons in silicon. Nature 571:371−375. DOI:10.1038/s41586-019-1381-2 |
| [3] | Chou C.-W., Kurz C., Hume D. B. et al. (2017). Preparation and coherent manipulation of pure quantum states of a single molecular ion. Nature 545:203−207. DOI:10.1038/nature22338 |
| [4] | Imre A., Csaba G., Ji L. et al. (2006). Majority logic gate for magnetic quantum-dot cellular automata. Science 311:205−208. DOI:10.1126/science.1120506 |
| [5] | Yan H., Lin Y., Wu H. et al. (2017). Bottom-up precise synthesis of stable platinum dimers on graphene. Nat. Commun. 8:1070. DOI:10.1038/s41467-017-01259-z |
| [6] | Kalff F. E., Rebergen M. P., Fahrenfort E. et al. (2016). A kilobyte rewritable atomic memory. Nat. Nanotechnol. 11:926−929. DOI:10.1038/nnano.2016.131 |
| [7] | Piquero-Zulaica I., Lobo-Checa J., Abd El-Fattah Z. M. et al. (2022). Engineering quantum states and electronic landscapes through surface molecular nanoarchitectures. Rev. Mod. Phys. 94:045008. DOI:10.1103/RevModPhys.94.045008 |
| [8] | Grill L., Dyer M., Lafferentz L. et al. (2007). Nano-architectures by covalent assembly of molecular building blocks. Nat. Nanotechnol. 2:687−691. DOI:10.1038/nnano.2007.346 |
| [9] | Chen Q., Bae S. C. and Granick S. (2011). Directed self-assembly of a colloidal kagome lattice. Nature 469:381−384. DOI:10.1038/nature09713 |
| [10] | Shang J., Wang Y., Chen M. et al. (2015). Assembling molecular Sierpiński triangle fractals. Nat. Chem. 7:389−393. DOI:10.1038/nchem.2211 |
| [11] | Chen J., Zhu E., Liu J. et al. (2018). Building two-dimensional materials one row at a time: Avoiding the nucleation barrier. Science 362:1135−1139. DOI:10.1126/science.aau4146 |
| [12] | Zhang Y.-Q., Paszkiewicz M., Du P. et al. (2018). Complex supramolecular interfacial tessellation through convergent multi-step reaction of a dissymmetric simple organic precursor. Nat. Chem. 10:296−304. DOI:10.1038/nchem.2924 |
| [13] | Montis R., Fusaro L., Falqui A. et al. (2021). Complex structures arising from the self-assembly of a simple organic salt. Nature 590:275−278. DOI:10.1038/s41586-021-03194-y |
| [14] | Fang H., Mahalingam H., Li X. et al. (2023). Atomically precise vacancy-assembled quantum antidots. Nat. Nanotechnol. 18:1401−1408. DOI:10.1038/s41565-023-01495-z |
| [15] | Crommie M. F., Lutz C. P. and Eigler D. M. (1993). Confinement of electrons to quantum corrals on a metal surface. Science 262:218−220. DOI:10.1126/science.262.5131.218 |
| [16] | Kim H. W., Han M., Shin H.-J. et al. (2011). Control of molecular rotors by selection of anchoring sites. Phys. Rev. Lett. 106:146101. DOI:10.1103/PhysRevLett.106.146101 |
| [17] | Gomes K. K., Mar W., Ko W. et al. (2012). Designer Dirac fermions and topological phases in molecular graphene. Nature 483:306−310. DOI:10.1038/nature10941 |
| [18] | Fölsch S., Martínez-Blanco J., Yang J. et al. (2014). Quantum dots with single-atom precision. Nat. Nanotechnol. 9:505−508. DOI:10.1038/nnano.2014.129 |
| [19] | Slot M. R., Gardenier T. S., Jacobse P. H. et al. (2017). Experimental realization and characterization of an electronic Lieb lattice. Nat. Phys. 13:672−676. DOI:10.1038/nphys4105 |
| [20] | Drost R., Ojanen T., Harju A. et al. (2017). Topological states in engineered atomic lattices. Nat. Phys. 13:668−671. DOI:10.1038/nphys4080 |
| [21] | Khajetoorians A. A., Wegner D., Otte A. F. et al. (2019). Creating designer quantum states of matter atom-by-atom. Nat. Rev. Phys. 1:703−715. DOI:10.1038/s42254-019-0108-5 |
| [22] | Chen I. J., Aapro M., Kipnis A. et al. (2022). Precise atom manipulation through deep reinforcement learning. Nat. Commun. 13:7499. DOI:10.1038/s41467-022-35149-w |
| [23] | Sierda E., Huang X., Badrtdinov D. I. et al. (2023). Quantum simulator to emulate lower-dimensional molecular structure. Science 380:1048−1052. DOI:10.1126/science.adf2685 |
| [24] | Calavalle F., Suárez-Rodríguez M., Martín-García B. et al. (2022). Gate-tuneable and chirality-dependent charge-to-spin conversion in tellurium nanowires. Nat. Mater. 21:526−532. DOI:10.1038/s41563-022-01211-7 |
| [25] | Ghosh P., Bhattacharjee J. and Waghmare U. V. (2008). The origin of stability of helical structure of tellurium. J. Phys. Chem. C 112:983−989. DOI:10.1021/jp077070d |
| [26] | Li X., Mitchell S., Fang Y. et al. (2023). Advances in heterogeneous single-cluster catalysis. Nat. Rev. Chem. 7:754−767. DOI:10.1038/s41570-023-00540-8 |
| [27] | Hu K.-J., Plant S. R., Ellis P. R. et al. (2015). Atomic resolution observation of a size-dependent change in the ripening modes of mass-selected Au nanoclusters involved in CO oxidation. J. Am. Chem. Soc. 137:15161−15168. DOI:10.1021/jacs.5b08720 |
| [28] | Li Z., Chen H.-Y. T., Schouteden K. et al. (2020). Unraveling the atomic structure, ripening behavior, and electronic structure of supported Au20 clusters. Sci. Adv. 6:eaay4289. DOI:10.1126/sciadv.aay4289 |
| [29] | Bonanni S., Aït-Mansour K., Harbich W. et al. (2012). Effect of the TiO2 reduction state on the catalytic CO oxidation on deposited size-selected Pt clusters. J. Am. Chem. Soc. 134:3445−3450. DOI:10.1021/ja2098854 |
| [30] | Haldar S., Vovusha H., Yadav M. K. et al. (2015). Systematic study of structural, electronic, and optical properties of atomic-scale defects in the two-dimensional transition metal dichalcogenides MX2 (M = Mo, W; X = S, Se, Te). Phys. Rev. B 92:235408. DOI:10.1103/PhysRevB.92.235408 |
| [31] | Zhao Y.-X., Jin H., Han Z.-Y. et al. (2025). Realization of fractional-layer transition metal dichalcogenides. Nat. Commun. 16:3659. DOI:10.1038/s41467-025-59007-7 |
| [32] | Lu W., Zhang Y., Zhu Z. et al. (2016). Thin tungsten telluride layer preparation by thermal annealing. Nanotechnology 27:414006. DOI:10.1088/0957-4484/27/41/414006 |
| [33] | Blades W. H., Frady N. J., Litwin P. M. et al. (2020). Thermally induced defects on WSe2. J. Phys. Chem. C 124:15337−15346. DOI:10.1021/acs.jpcc.0c04440 |
| [34] | Evans P. E., Wang Y., Sushko P. V. et al. (2023). Understanding palladium-tellurium cluster formation on WTe2: From a kinetically hindered distribution to thermodynamically controlled monodispersity. PNAS Nexus 2:pgad212. DOI:10.1093/pnasnexus/pgad212 |
| [35] | Sugawara K., Gotoh T. and Tanaka K. (2004). Nanoscale phase change in telluride films induced with scanning tunneling microscopes. Jpn. J. Appl. Phys. 43:L676. DOI:10.1143/JJAP.43.L676 |
| [36] | Ren Y.-N., Zhang M.-H., Zhou X.-F. et al. (2024). In situ creation and tailoring of interfacial quantum dots in graphene/transition metal dichalcogenide heterostructures. Phys. Rev. B 110:125416. DOI:10.1103/PhysRevB.110.125416 |
| [37] | Degtyareva O., Gregoryanz E., Somayazulu M. et al. (2005). Novel chain structures in group VI elements. Nat. Mater. 4:152−155. DOI:10.1038/nmat1294 |
| [38] | Jin Y., Maroulis G., Kuang X. et al. (2015). Geometries, stabilities and fragmental channels of neutral and charged sulfur clusters: SnQ (n = 3-20, Q = 0, ±1). Phys. Chem. Chem. Phys. 17:13590−13597. DOI:10.1039/C5CP00728C |
| [39] | Millefiori S. and Alparone A. (2001). Ab initio study of the structure and polarizability of sulfur clusters, Sn (n = 2-12). J. Phys. Chem. A 105:9489−9497. DOI:10.1021/jp0121466 |
| [40] | Alexander A. D. and Otto F. S. (2001). Theory of zeolite supralattices: Se in zeolite Linde type A. J. Phys.: Condens. Matter 13:10433. DOI:10.1088/0953-8984/13/46/313 |
| [41] | Guo J., Meng X., Chen J. et al. (2014). Real-space imaging of interfacial water with submolecular resolution. Nat. Mater. 13:184−189. DOI:10.1038/nmat3848 |
| [42] | Kowalczyk H., Biscaras J., Pistawala N. et al. (2023). Gate and temperature driven phase transitions in few-layer MoTe2. ACS Nano 17:6708−6718. DOI:10.1021/acsnano.2c12610 |
| [43] | Pawbake A., Bellin C., Paulatto L. et al. (2019). Pressure-induced phase transitions in germanium telluride: Raman signatures of anharmonicity and oxidation. Phys. Rev. Lett. 122:145701. DOI:10.1103/PhysRevLett.122.145701 |
| [44] | Kresse G. and Furthmüller J. (1996). Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6:15−50. DOI:10.1016/0927-0256(96)00008-0 |
| [45] | Kresse G. and Furthmüller J. (1996). Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54:11169−11186. DOI:10.1103/PhysRevB.54.11169 |
| [46] | Blöchl P. E. (1994). Projector augmented-wave method. Phys. Rev. B 50:17953−17979. DOI:10.1103/PhysRevB.50.17953 |
| [47] | Kresse G. and Joubert D. (1999). From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59:1758−1775. DOI:10.1103/PhysRevB.59.1758 |
| [48] | Perdew J. P., Burke K. and Ernzerhof M. (1996). Generalized gradient approximation made simple. Phys. Rev. Lett. 77:3865−3868. DOI:10.1103/PhysRevLett.77.3865 |
| [49] | Tersoff J. and Hamann D. R. (1983). Theory and application for the scanning tunneling microscope. Phys. Rev. Lett. 50:1998−2001. DOI:10.1103/PhysRevLett.50.1998 |
| [50] | Tersoff J. and Hamann D. R. (1985). Theory of the scanning tunneling microscope. Phys. Rev. B 31:805−813. DOI:10.1103/PhysRevB.31.805 |
| Han Z.-Y., Zhao X., Zhao Y.-X., et al. (2026). Self-assembly and manipulation of Te clusters on WTe2 surface. The Innovation Physics 1:100008. https://doi.org/10.59717/j.tip.2026.100008 |
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Atomic-precision self-assembly of Te clusters on the 1T’-WTe2 surface
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