Article Contents
ARTICLE   Open Access     Cite

Schottky infrared detectors with optically tunable barriers beyond the internal photoemission limit

More Information
  • Corresponding author: weixingzhan@cigit.ac.cn
  • DownLoad: Full size image
    1. ■ An infrared detector with an optically tunable barrier is proposed to overcome the internal photoemission limit.
    2. ■ Broadband infrared detection is attained while maintaining a low dark current.
    3. ■ Highly sensitive blackbody radiation sensing is achieved at room temperature.
    4. ■ This strategy shows promise for realizing uncooled, high-performance silicon-based infrared sensors.
  • Internal photoemission is a prominent branch of the photoelectric effect and has emerged as a viable method for detecting photons with energies below the semiconductor bandgap. This breakthrough has played a significant role in accelerating the development of infrared imaging in one chip with stateof-the-art silicon techniques. However, the performance of these Schottky infrared detectors is currently hindered by the limit of internal photoemission; specifically, a low Schottky barrier height is inevitable for the detection of low-energy infrared photons. Herein, a distinct paradigm of Schottky infrared detectors is proposed to overcome the internal photoemission limit by introducing an optically tunable barrier. This device uses an infrared absorbing material-sensitized Schottky diode, assisted by the highly adjustable Fermi level of graphene, which subtly decouples the photon energy from the Schottky barrier height. Correspondingly, a broadband photoresponse spanning from ultraviolet to mid-wave infrared is achieved, with a high specific detectivity of 9.83 × 3 1010 cm Hz1/2 W–1 at 2,700 nm and an excellent specific detectivity of 7.2 × 3 109 cm Hz1/2 W–1 at room temperature under blackbody radiation. These results address a key challenge in internal photoemission and hold great promise for the development of the Schottky infrared detector with high sensitivity and room temperature operation.
  • 加载中
  • [1] Casalino, M. (2016). Internal Photoemission Theory: Comments and Theoretical Limitations on the Performance of Near-Infrared Silicon Schottky Photodetectors. IEEE J. Quant. Electron. 52(4): 1–10. https://doi.org/10.1109/jqe.2016.2532866.

    View in Article CrossRef Google Scholar

    [2] Scales, C., and Berini, P. (2010). Thin-Film Schottky Barrier Photodetector Models. IEEE J. Quant. Electron. 46(5): 633–643. https://doi.org/10.1109/jqe.2010.2046720.

    View in Article CrossRef Google Scholar

    [3] Massicotte, M., Schmidt, P., Vialla, F., et al. (2016). Photo-thermionic effect in vertical graphene heterostructures. Nat. Commun. 7: 12174. https://doi.org/10.1038/ncomms12174.

    View in Article CrossRef Google Scholar

    [4] Rogalski, A. (2000). Infrared detectors (CRC press).

    View in Article Google Scholar

    [5] Brongersma, M.L., Halas, N.J., and Nordlander, P. (2015). Plasmon-induced hot carrier science and technology. Nat. Nanotechnol. 10(1): 25–34. https://doi.org/10.1038/nnano.2014.311.

    View in Article CrossRef Google Scholar

    [6] Zhao, W., Yan, Y., Chen, X., et al. (2022). Combining printing and nanoparticle assembly: Methodology and application of nanoparticle patterning. Innovation 3(4): 100253. https://doi.org/10.1016/j.xinn.2022.100253.

    View in Article CrossRef Google Scholar

    [7] Wang, W.S., Ho, C., and Chuang, T.M. (1998). High-performance IR Detectors Fabricated by PtSi on P-Si Substrate. In Infrared Detectors and Focal Plane Arrays V.

    View in Article Google Scholar

    [8] Casalino, M., Sirleto, L., Moretti, L., et al. (2009). Back-illuminated silicon resonant cavity-enhanced photodetector at 1550 nm. Phys. E Low-dimens. Syst. Nanostruct. 41(6): 1097–1101. https://doi.org/10.1016/j.physe.2008.08.049.

    View in Article CrossRef Google Scholar

    [9] Zhu, S., Yu, M.B., Lo, G.Q., et al. (2008). Near-infrared waveguide-based nickel silicide Schottky-barrier photodetector for optical communications. Appl. Phys. Lett. 92(8): 081103. https://doi.org/10.1063/1.2885089.

    View in Article CrossRef Google Scholar

    [10] Knight, M.W., Sobhani, H., Nordlander, P., et al. (2011). Photodetection with Active Optical Antennas. Science 332(6030): 702–704. https://doi.org/10.1126/science.1203056.

    View in Article CrossRef Google Scholar

    [11] Akbari, A., Tait, R.N., and Berini, P. (2010). Surface plasmon waveguide Schottky detector. Opt Express 18(8): 8505–8514. https://doi.org/10.1364/OE.18.008505.

    View in Article CrossRef Google Scholar

    [12] Desiatov, B., Goykhman, I., Mazurski, N., et al. (2015). Plasmonic enhanced silicon pyramids for internal photoemission Schottky detectors in the near-infrared regime. Optica 2(4): 335–338. https://doi.org/10.1364/optica.2.000335.

    View in Article CrossRef Google Scholar

    [13] Steglich, M., Zilk, M., Bingel, A., et al. (2013). A normal-incidence PtSi photoemissive detector with black silicon light-trapping. J. Appl. Phys. 114(18): 183102. https://doi.org/10.1063/1.4829897.

    View in Article CrossRef Google Scholar

    [14] Amirmazlaghani, M., Raissi, F., Habibpour, O., et al. (2013). Graphene-Si Schottky IR Detector. IEEE J. Quant. Electron. 49(7): 589–594. https://doi.org/10.1109/jqe.2013.2261472.

    View in Article CrossRef Google Scholar

    [15] Casalino, M. (2019). Silicon Meets Graphene for a New Family of Near-Infrared Schottky Photodetectors. Appl. Sci. 9(18): 3677. https://doi.org/10.3390/app9183677.

    View in Article CrossRef Google Scholar

    [16] Li, X., Chen, X., Li, S., et al. (2021). High performance sub-bandgap photodetection via internal photoemission based on ideal metal/2D-material van der Waals Schottky interface. Nanoscale 13(39): 16448–16456. https://doi.org/10.1039/d1nr04770a.

    View in Article CrossRef Google Scholar

    [17] Wang, F., Zhang, T., Xie, R., et al. (2023). How to characterize figures of merit of two-dimensional photodetectors. Nat. Commun. 14(1): 2224. https://doi.org/10.1038/s41467-023-37635-1.

    View in Article CrossRef Google Scholar

    [18] Lee, S.-J., Cheng, H.-C., Wang, Y., et al. (2023). Lead halide perovskite sensitized WSe2 photodiodes with ultrahigh open circuit voltages. eLight 3(1): 8. https://doi.org/10.1186/s43593-023-00040-8.

    View in Article CrossRef Google Scholar

    [19] Guo, Z., Zeng, Y., Meng, F., et al. (2022). In-situ neutron-transmutation for substitutional doping in 2D layered indium selenide based phototransistor. eLight 2(1): 9. https://doi.org/10.1186/s43593-022-00017-z.

    View in Article CrossRef Google Scholar

    [20] Jiang, H., Wei, J., Sun, F., et al. (2022). Enhanced Photogating Effect in Graphene Photodetectors via Potential Fluctuation Engineering. ACS Nano 16(3): 4458–4466. https://doi.org/10.1021/acsnano.1c10795.

    View in Article CrossRef Google Scholar

    [21] Wei, J., Xu, C., Dong, B., et al. (2021). Mid-infrared semimetal polarization detectors with configurable polarity transition. Nat. Photonics 15(8): 614–621. https://doi.org/10.1038/s41566-021-00819-6.

    View in Article CrossRef Google Scholar

    [22] Zhan, H.E., Xiao-dong, W.E.I., Chun-feng, C.A.I., et al. (2010). PbTe thin film mid-infrared photoconductive detectors grown by molecular beam epitaxy. Infrared Laser Eng. 39(1): 22–25.

    View in Article Google Scholar

    [23] Wang, X.-J., Zou, L., Li, D., et al. (2015). Photo-Induced Doping in Graphene/Silicon Heterostructures. J. Phys. Chem. 119(2): 1061–1066. https://doi.org/10.1021/jp509878m.

    View in Article CrossRef Google Scholar

    [24] Ju, L.,, Huang, E., et al. (2014). Photoinduced doping in heterostructures of graphene and boron nitride. Nat. Nanotechnol. 9(5): 348–352. https://doi.org/10.1038/nnano.2014.60.

    View in Article CrossRef Google Scholar

    [25] An, X., Liu, F., Jung, Y.J., et al. (2013). Tunable graphene-silicon heterojunctions for ultrasensitive photodetection. Nano Lett. 13(3): 909–916. https://doi.org/10.1021/nl303682j.

    View in Article CrossRef Google Scholar

    [26] Tang, Y., Li, R., Sun, R., et al. (2023). Flexible all-organic photodetectors via universal water-assisted transfer printing. Innovation 4(4): 100460. https://doi.org/10.1016/j.xinn.2023.100460.

    View in Article CrossRef Google Scholar

    [27] Chen, C.K., Nechay, B., and Tsaur, B.Y. (1991). Ultraviolet, Visible, and Infrared Response of PtSi Schottky-Barrier Detectors Operated in the Front-illuminated Mode. IEEE Trans. Electron. Dev. 38(5): 1094–1103. https://doi.org/10.1109/16.78384.

    View in Article CrossRef Google Scholar

    [28] Wu, J.H., Chang, R.S., and Horng, G.J. (2004). Microstructure, electrical, and optical properties of evaporated PtSi/p-Si(100) Schottky barriers as high quantum efficient infrared detectors. Thin Solid Films 466(1–2): 314–319. https://doi.org/10.1016/j.tsf.2004.03.016.

    View in Article CrossRef Google Scholar

    [29] Wang, F., Liu, Z., Zhang, T., et al. (2022). Fully Depleted Self-Aligned Heterosandwiched Van Der Waals Photodetectors. Adv. Mater. 34(39): e2203283. https://doi.org/10.1002/adma.202203283.

    View in Article CrossRef Google Scholar

    [30] Wang, F., Zhang, T., Xie, R., et al. (2024). Next-generation Photodetectors Beyond van der Waals Junctions. Adv. Mater. 36: e2301197. https://doi.org/10.1002/adma.202301197.

    View in Article CrossRef Google Scholar

    [31] Li, C., Wang, H., Wang, F., et al. (2020). Ultrafast and broadband photodetectors based on a perovskite/organic bulk heterojunction for large-dynamic-range imaging. Light Sci. Appl. 9: 31. https://doi.org/10.1038/s41377-020-0264-5.

    View in Article CrossRef Google Scholar

    [32] Wang, H., Li, Z., Li, D., et al. (2021). Junction Field-Effect Transistors Based on PdSe2/MoS2 Heterostructures for Photodetectors Showing High Responsivity and Detectivity. Adv. Funct. Mater. 31(49): 2106105. https://doi.org/10.1002/adfm.202106105.

    View in Article CrossRef Google Scholar

    [33] Hu, W., Ye, Z., Liao, L., et al. (2014). 128x128 long-wavelength/mid-wavelength two-color HgCdTe infrared focal plane array detector with ultralow spectral cross talk. Opt. Lett. 39(17): 5184–5187. https://doi.org/10.1364/OL.39.005184.

    View in Article CrossRef Google Scholar

    [34] Hu, W.D., Chen, X.S., Ye, Z.H., et al. (2011). A hybrid surface passivation on HgCdTe long wave infrared detector with in-situ CdTe deposition and high-density hydrogen plasma modification. Appl. Phys. Lett. 99(9): 091101. https://doi.org/10.1063/1.3633103.

    View in Article CrossRef Google Scholar

    [35] Xiang, D., Han, C., Hu, Z., et al. (2015). Surface Transfer Doping-Induced, High-Performance Graphene/Silicon Schottky Junction-Based, Self-Powered Photodetector. Small 11(37): 4829–4836. https://doi.org/10.1002/smll.201501298.

    View in Article CrossRef Google Scholar

    [36] Xu, A., Yang, S., Liu, Z., et al. (2018). Near-infrared photodetector based on Schottky junctions of monolayer graphene/GeOI. Mater. Lett. 227: 17–20. https://doi.org/10.1016/j.matlet.2018.04.107.

    View in Article CrossRef Google Scholar

    [37] Yu, T., Wang, F., Xu, Y., et al. (2016). Graphene Coupled with Silicon Quantum Dots for High-Performance Bulk-Silicon-Based Schottky-Junction Photodetectors. Adv. Mater. 28(24): 4912–4919. https://doi.org/10.1002/adma.201506140.

    View in Article CrossRef Google Scholar

    [38] Riazimehr, S., Kataria, S., Bornemann, R., et al. (2017). High Photocurrent in Gated Graphene-Silicon Hybrid Photodiodes. ACS Photonics 4(6): 1506–1514. https://doi.org/10.1021/acsphotonics.7b00285.

    View in Article CrossRef Google Scholar

    [39] Casalino, M., Russo, R., Russo, C., et al. (2018). Free-Space Schottky Graphene/Silicon Photodetectors Operating at 2 um. ACS Photonics 5(11): 4577–4585. https://doi.org/10.1021/acsphotonics.8b01037.

    View in Article CrossRef Google Scholar

    [40] Kim, J.W., Kim, C.Y., Kim, J.H., et al. (2021). Highly responsive near-infrared photodetector with low dark current using graphene/germanium Schottky junction with Al2O3 interfacial layer. Pathogens 10(5): 1573–1579. https://doi.org/10.1515/nanoph-2021-0002.

    View in Article CrossRef Google Scholar

    [41] Kim, W., Arpiainen, S., Xue, H., et al. (2018). Photoresponse of Graphene-Gated Graphene-GaSe Heterojunction Devices. ACS Appl. Nano Mater. 1(8): 3895–3902. https://doi.org/10.1021/acsanm.8b00684.

    View in Article CrossRef Google Scholar

    [42] Xu, J., Liu, T., Hu, H., et al. (2020). Design and optimization of tunneling photodetectors based on graphene/Al2O3/silicon heterostructures. Nanophotonics 9(12): 3841–3848. https://doi.org/10.1515/nanoph-2019-0499.

    View in Article CrossRef Google Scholar

    [43] Won, U.Y., Lee, B.H., Kim, Y.R., et al. (2020). Efficient photovoltaic effect in graphene/h-BN/silicon heterostructure self-powered photodetector. Nano Res. 14(6): 1967–1972. https://doi.org/10.1007/s12274-020-2866-x.

    View in Article CrossRef Google Scholar

    [44] Tang, X., Chen, M., Kamath, A., et al. (2020). Colloidal Quantum-Dots/Graphene/Silicon Dual-Channel Detection of Visible Light and Short-Wave Infrared. ACS Photonics 7(5): 1117–1121. https://doi.org/10.1021/acsphotonics.0c00247.

    View in Article CrossRef Google Scholar

    [45] Pospischil, A., Humer, M., Furchi, M.M., et al. (2013). CMOS-compatible graphene photodetector covering all optical communication bands. Nat. Photonics 7(11): 892–896. https://doi.org/10.1038/nphoton.2013.240.

    View in Article CrossRef Google Scholar

    [46] Furchi, M., Urich, A., Pospischil, A., et al. (2012). Microcavity-integrated graphene photodetector. Nano Lett. 12(6): 2773–2777. https://doi.org/10.1021/nl204512x.

    View in Article CrossRef Google Scholar

    [47] Lemme, M.C., Koppens, F.H.L., Falk, A.L., et al. (2011). Gate-activated photoresponse in a graphene p-n junction. Nano Lett. 11(10): 4134–4137. https://doi.org/10.1021/nl2019068.

    View in Article CrossRef Google Scholar

    [48] Kim, C.O., Kim, S., Shin, D.H., et al. (2014). High photoresponsivity in an all-graphene p-n vertical junction photodetector. Nat. Commun. 5: 3249. https://doi.org/10.1038/ncomms4249.

    View in Article CrossRef Google Scholar

    [49] An, Y., Behnam, A., Pop, E., et al. (2013). Metal-semiconductor-metal photodetectors based on graphene/p-type silicon Schottky junctions. Appl. Phys. Lett. 102(1): 013110. https://doi.org/10.1063/1.4773992.

    View in Article CrossRef Google Scholar

    [50] Xia, F., Mueller, T., Lin, Y.M., et al. (2009). Ultrafast graphene photodetector. Nat. Nanotechnol. 4(12): 839–843. https://doi.org/10.1038/nnano.2009.292.

    View in Article CrossRef Google Scholar

    [51] Mueller, T., Xia, F., and Avouris, P. (2010). Graphene photodetectors for high-speed optical communications. Nat. Photonics 4(5): 297–301. https://doi.org/10.1038/nphoton.2010.40.

    View in Article CrossRef Google Scholar

    [52] Li, X., Zhu, M., Du, M., et al. (2016). High Detectivity Graphene-Silicon Heterojunction Photodetector. Small 12(5): 595–601. https://doi.org/10.1002/smll.201502336.

    View in Article CrossRef Google Scholar

    [53] Almeida, J.M., Wisniowski, P., and Freitas, P.P. (2008). Low-Frequency Noise in MgO Magnetic Tunnel Junctions: Hooge's Parameter Dependence on Bias Voltage. IEEE Trans. Magn. 44(11): 2569–2572. https://doi.org/10.1109/tmag.2008.2002604.

    View in Article CrossRef Google Scholar

    [54] Wu, P., Ye, L., Tong, L., et al. (2022). Van der Waals two-color infrared photodetector. Light Sci. Appl. 11(1): 6. https://doi.org/10.1038/s41377-021-00694-4.

    View in Article CrossRef Google Scholar

    [55] Chen, Y., Wang, Y., Wang, Z., et al. (2021). Unipolar barrier photodetectors based on van der Waals heterostructures. Nat. Electron. 4(5): 357–363. https://doi.org/10.1038/s41928-021-00586-w.

    View in Article CrossRef Google Scholar

    [56] Zou, X., Xu, Y., and Duan, W. (2021). 2D materials: Rising star for future applications. Innovation 2(2): 100115. https://doi.org/10.1016/j.xinn.2021.100115.

    View in Article CrossRef Google Scholar

    [57] Wei, J., Chen, Y., Li, Y., et al. (2022). Geometric filterless photodetectors for mid-infrared spin light. Nat. Photonics 17(2): 171–178. https://doi.org/10.1038/s41566-022-01115-7.

    View in Article CrossRef Google Scholar

    [58] Guo, Z., Zhang, Z., Yan, R., et al. (2022). Electrochemical epitaxial PbTe nanowires photodetector for NIR response. Nanotechnology 33(48): 485202. https://doi.org/10.1088/1361-6528/ac8b17.

    View in Article CrossRef Google Scholar

  • Cite this article:

    Fu J., Guo Z., Nie C., et al., (2024). Schottky infrared detectors with optically tunable barriers beyond the internal photoemission limit. The Innovation 5(3), 100600. https://doi.org/10.1016/j.xinn.2024.100600
    Fu J., Guo Z., Nie C., et al., (2024). Schottky infrared detectors with optically tunable barriers beyond the internal photoemission limit. The Innovation 5(3), 100600. https://doi.org/10.1016/j.xinn.2024.100600

Welcome!

To request copyright permission to republish or share portions of our works, please visit Copyright Clearance Center's (CCC) Marketplace website at marketplace.copyright.com.

Figures(5)    

Share

  • Share the QR code with wechat scanning code to friends and circle of friends.

Article Metrics

Article views(3973) PDF downloads(1879)

Relative Articles

Cited by

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint